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Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

Lloyd BA, Arif AM - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group.The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°.The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane.

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Affiliation: Department of Chemistry, Weber State University, Ogden, Utah 84408-2503.

ABSTRACT
The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings.

No MeSH data available.


ORTEP-3 drawing of the title compound showing 50% displacement ellipsoids.
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Fap1: ORTEP-3 drawing of the title compound showing 50% displacement ellipsoids.


Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

Lloyd BA, Arif AM - Acta Crystallogr Sect E Struct Rep Online (2012)

ORTEP-3 drawing of the title compound showing 50% displacement ellipsoids.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515191&req=5

Fap1: ORTEP-3 drawing of the title compound showing 50% displacement ellipsoids.
Bottom Line: The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group.The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°.The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Weber State University, Ogden, Utah 84408-2503.

ABSTRACT
The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl-ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl-ate group and the norbornyl methano C-O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol-ecules pack as pairs of enanti-omers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings.

No MeSH data available.