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N-[4-(2-Propyn-1-yl-oxy)phen-yl]acetamide.

Belay YH, Kinfe HH, Muller A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(11)H(11)NO(2), was synthesized by chemoselective N-acetyl-ation of 4-amino-phenol followed by reaction with propargyl bromide in the presence of K(2)CO(3). the acetamide and propyn-1-yloxy substituents form dihedral angles of 18.31 (6) and 7.01 (10)°, respectively, with the benzene ring.In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into chains along [010].C-H⋯O and C-H⋯π inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, C(11)H(11)NO(2), was synthesized by chemoselective N-acetyl-ation of 4-amino-phenol followed by reaction with propargyl bromide in the presence of K(2)CO(3). the acetamide and propyn-1-yloxy substituents form dihedral angles of 18.31 (6) and 7.01 (10)°, respectively, with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into chains along [010]. C-H⋯O and C-H⋯π inter-actions also occur.

No MeSH data available.


Related in: MedlinePlus

Packing diagram showing the molecules linked by infinite one-dimensional N—H···O chains in the [010] direction. Hydrogen bonds and C—H···O/π interactions are shown as red and black dashed lines respectively.
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Fap2: Packing diagram showing the molecules linked by infinite one-dimensional N—H···O chains in the [010] direction. Hydrogen bonds and C—H···O/π interactions are shown as red and black dashed lines respectively.


N-[4-(2-Propyn-1-yl-oxy)phen-yl]acetamide.

Belay YH, Kinfe HH, Muller A - Acta Crystallogr Sect E Struct Rep Online (2012)

Packing diagram showing the molecules linked by infinite one-dimensional N—H···O chains in the [010] direction. Hydrogen bonds and C—H···O/π interactions are shown as red and black dashed lines respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515179&req=5

Fap2: Packing diagram showing the molecules linked by infinite one-dimensional N—H···O chains in the [010] direction. Hydrogen bonds and C—H···O/π interactions are shown as red and black dashed lines respectively.
Bottom Line: The title compound, C(11)H(11)NO(2), was synthesized by chemoselective N-acetyl-ation of 4-amino-phenol followed by reaction with propargyl bromide in the presence of K(2)CO(3). the acetamide and propyn-1-yloxy substituents form dihedral angles of 18.31 (6) and 7.01 (10)°, respectively, with the benzene ring.In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into chains along [010].C-H⋯O and C-H⋯π inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg, 2006, South Africa.

ABSTRACT
The title compound, C(11)H(11)NO(2), was synthesized by chemoselective N-acetyl-ation of 4-amino-phenol followed by reaction with propargyl bromide in the presence of K(2)CO(3). the acetamide and propyn-1-yloxy substituents form dihedral angles of 18.31 (6) and 7.01 (10)°, respectively, with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into chains along [010]. C-H⋯O and C-H⋯π inter-actions also occur.

No MeSH data available.


Related in: MedlinePlus