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Poly[(μ(3)-hydrogenphosphato)(4H-1,2,4-triazole-κN(1))zinc].

Aitenneite H, El Bouari A, Sebti S, Saadi M, El Ammari L, Adil K - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring.Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane.Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie des Matériaux Solides, Faculté des Sciences Ben M'sik Casablanca, Morocco.

ABSTRACT
The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2-) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

No MeSH data available.


Related in: MedlinePlus

A three dimensional view of the (C2H3N3)ZnHPO4 framework structure showing a stacking of the inorganic and organic layers. The PO4 tetrahedron is shown in pink and the ZnO3N tetrahedron is blue green. Hydrogen bonds are drawn as dashed lines.
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Fap2: A three dimensional view of the (C2H3N3)ZnHPO4 framework structure showing a stacking of the inorganic and organic layers. The PO4 tetrahedron is shown in pink and the ZnO3N tetrahedron is blue green. Hydrogen bonds are drawn as dashed lines.


Poly[(μ(3)-hydrogenphosphato)(4H-1,2,4-triazole-κN(1))zinc].

Aitenneite H, El Bouari A, Sebti S, Saadi M, El Ammari L, Adil K - Acta Crystallogr Sect E Struct Rep Online (2012)

A three dimensional view of the (C2H3N3)ZnHPO4 framework structure showing a stacking of the inorganic and organic layers. The PO4 tetrahedron is shown in pink and the ZnO3N tetrahedron is blue green. Hydrogen bonds are drawn as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515161&req=5

Fap2: A three dimensional view of the (C2H3N3)ZnHPO4 framework structure showing a stacking of the inorganic and organic layers. The PO4 tetrahedron is shown in pink and the ZnO3N tetrahedron is blue green. Hydrogen bonds are drawn as dashed lines.
Bottom Line: The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring.Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane.Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie des Matériaux Solides, Faculté des Sciences Ben M'sik Casablanca, Morocco.

ABSTRACT
The asymmetric unit of the title compound, [Zn(HPO(4))(C(2)H(3)N(3))](n), contains one Zn(2+) cation, one (HPO(4))(2-) anion and a 1,2,4 triazole ligand. The Zn(2+) cation is coordinated in a quite regular tetra-hedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three Zn(II) cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

No MeSH data available.


Related in: MedlinePlus