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catena-Poly[[[aqua-(2,2'-bipyridine-κ(2)N,N')copper(II)]-μ-furan-2,5-di-carboxyl-ato-κ(2)O(2):O(5)] dihydrate].
Bottom Line:
The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position.The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88 (7)°.O(water)-H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001).
Affiliation: School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.
ABSTRACT
In the crystal structure of the title compound, {[Cu(C(6)H(2)O(5))(C(10)H(8)N(2))(H(2)O)]·2H(2)O}(n), an infinite chain parallel to [110] is formed by the linking of Cu(H(2)O)(2,2'-bipyridine) units through a furan-2,5-dicarboxyl-ate bridge. The Cu(II) atom shows a square-pyramidal geometry, with one furan-2,5-dicarboxyl-ate O atom in the apical position. The dihedral angle between the planes of the furan ring and the bipyridine mol-ecule is 83.88 (7)°. O(water)-H⋯O hydrogen bonds connect adjacent chains, generating a layer motif parallel to (001). No MeSH data available. |
![The unit cell of (I), showing the atomic labelling scheme and displacement ellipsoids at the 50% probability level. [Symmetry codes: (i) -1 + x, 1 + y, z.]](/imgs/512/388/3515153/PMC3515153_e-68-m1416-fig1.png)
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Fap1: The unit cell of (I), showing the atomic labelling scheme and displacement ellipsoids at the 50% probability level. [Symmetry codes: (i) -1 + x, 1 + y, z.] |
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Affiliation: School of Chemical Engineering, Changchun University of Technology, Changchun 130012, People's Republic of China.
No MeSH data available.
