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Bis(benzene-1,2-diamine-κ(2)N,N')(sulfato-κO)copper(II) monohydrate.

Djebli Y, Boufas S, Bencharif L, Roisnel T, Bencharif M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two benzene-1,2-diamine ligands at the base and one O atom from a monodentate sulfate anion at the apex of the coordination polyhedron.N-H⋯O hydrogen bonding between the amino functions and the sulfate groups leads to the formation of layers parallel to (001).There are voids in the structure filled with lattice water mol-ecules that are disordered over three sites in a 0.430 (6):0.270 (6):0.300 (6) ratio.

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Affiliation: Université Mentouri de Constantine, 25000 Constantine, Algeria.

ABSTRACT
The title complex, [Cu(SO(4))(C(6)H(8)N(2))(2)]·H(2)O, was obtained under hydro-thermal conditions. The Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two benzene-1,2-diamine ligands at the base and one O atom from a monodentate sulfate anion at the apex of the coordination polyhedron. N-H⋯O hydrogen bonding between the amino functions and the sulfate groups leads to the formation of layers parallel to (001). C-H⋯O hydrogen bonding inter-actions between the layers consolidate the three-dimensional set-up. There are voids in the structure filled with lattice water mol-ecules that are disordered over three sites in a 0.430 (6):0.270 (6):0.300 (6) ratio.

No MeSH data available.


Related in: MedlinePlus

Part of the crystal structure of (I), showing the formation of R22(8), R21(4),hy2596 R12(6) and R33(9) rings. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in the motif have been omitted for clarity.
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Fap2: Part of the crystal structure of (I), showing the formation of R22(8), R21(4),hy2596 R12(6) and R33(9) rings. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in the motif have been omitted for clarity.


Bis(benzene-1,2-diamine-κ(2)N,N')(sulfato-κO)copper(II) monohydrate.

Djebli Y, Boufas S, Bencharif L, Roisnel T, Bencharif M - Acta Crystallogr Sect E Struct Rep Online (2012)

Part of the crystal structure of (I), showing the formation of R22(8), R21(4),hy2596 R12(6) and R33(9) rings. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in the motif have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515150&req=5

Fap2: Part of the crystal structure of (I), showing the formation of R22(8), R21(4),hy2596 R12(6) and R33(9) rings. Hydrogen bonds are shown as dashed lines. Hydrogen atoms not involved in the motif have been omitted for clarity.
Bottom Line: The Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two benzene-1,2-diamine ligands at the base and one O atom from a monodentate sulfate anion at the apex of the coordination polyhedron.N-H⋯O hydrogen bonding between the amino functions and the sulfate groups leads to the formation of layers parallel to (001).There are voids in the structure filled with lattice water mol-ecules that are disordered over three sites in a 0.430 (6):0.270 (6):0.300 (6) ratio.

View Article: PubMed Central - HTML - PubMed

Affiliation: Université Mentouri de Constantine, 25000 Constantine, Algeria.

ABSTRACT
The title complex, [Cu(SO(4))(C(6)H(8)N(2))(2)]·H(2)O, was obtained under hydro-thermal conditions. The Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two benzene-1,2-diamine ligands at the base and one O atom from a monodentate sulfate anion at the apex of the coordination polyhedron. N-H⋯O hydrogen bonding between the amino functions and the sulfate groups leads to the formation of layers parallel to (001). C-H⋯O hydrogen bonding inter-actions between the layers consolidate the three-dimensional set-up. There are voids in the structure filled with lattice water mol-ecules that are disordered over three sites in a 0.430 (6):0.270 (6):0.300 (6) ratio.

No MeSH data available.


Related in: MedlinePlus