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Hexa-kis-(μ(3)-1-methyl-thio-urea-κ(3)S:S:S)hexa-kis-[iodidocopper(I)].

Ahmad S, Mufakkar M, Khan IU, Fun HK, Waheed A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile.The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry.The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry.

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Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry. The crystal structure is stabilized by N-H⋯I hydrogen bonds and cuprophilic inter-actions [Cu⋯Cu = 3.0264 (9) Å].

No MeSH data available.


Molecular structure of the title compound with displacement ellipsoids drawn at 50% probability level. Symmetry codes: (a) 1-y, 2+x-y, z; (b) -1-x+y, 1-x, z; (c) -x, 2-y, -z; (d) -1+y, -x+y, -z; (e) 1+x-y, 1+x, -z.
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Fap1: Molecular structure of the title compound with displacement ellipsoids drawn at 50% probability level. Symmetry codes: (a) 1-y, 2+x-y, z; (b) -1-x+y, 1-x, z; (c) -x, 2-y, -z; (d) -1+y, -x+y, -z; (e) 1+x-y, 1+x, -z.


Hexa-kis-(μ(3)-1-methyl-thio-urea-κ(3)S:S:S)hexa-kis-[iodidocopper(I)].

Ahmad S, Mufakkar M, Khan IU, Fun HK, Waheed A - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title compound with displacement ellipsoids drawn at 50% probability level. Symmetry codes: (a) 1-y, 2+x-y, z; (b) -1-x+y, 1-x, z; (c) -x, 2-y, -z; (d) -1+y, -x+y, -z; (e) 1+x-y, 1+x, -z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515146&req=5

Fap1: Molecular structure of the title compound with displacement ellipsoids drawn at 50% probability level. Symmetry codes: (a) 1-y, 2+x-y, z; (b) -1-x+y, 1-x, z; (c) -x, 2-y, -z; (d) -1+y, -x+y, -z; (e) 1+x-y, 1+x, -z.
Bottom Line: The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile.The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry.The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry. The crystal structure is stabilized by N-H⋯I hydrogen bonds and cuprophilic inter-actions [Cu⋯Cu = 3.0264 (9) Å].

No MeSH data available.