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(Nitrato-κO)tris-[tris-(4-fluoro-phen-yl)phosphane-κP]copper(I).

Hill TN, Roodt A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position.The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H⋯F and C-H⋯O inter-actions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.

ABSTRACT
In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H⋯F and C-H⋯O inter-actions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.

No MeSH data available.


Inter- and intramolecular C—H···O interactions (dashed bonds) for I. Symmetry code (iii) x - 1, y, z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.
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Fap4: Inter- and intramolecular C—H···O interactions (dashed bonds) for I. Symmetry code (iii) x - 1, y, z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.


(Nitrato-κO)tris-[tris-(4-fluoro-phen-yl)phosphane-κP]copper(I).

Hill TN, Roodt A - Acta Crystallogr Sect E Struct Rep Online (2012)

Inter- and intramolecular C—H···O interactions (dashed bonds) for I. Symmetry code (iii) x - 1, y, z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515141&req=5

Fap4: Inter- and intramolecular C—H···O interactions (dashed bonds) for I. Symmetry code (iii) x - 1, y, z. Non-relevant hydrogen atoms and phenyl rings have been omitted for clarity.
Bottom Line: In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position.The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H⋯F and C-H⋯O inter-actions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.

ABSTRACT
In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular π-π inter-action [centroid-centroid distance = 3.6113 (11) Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H⋯F and C-H⋯O inter-actions with distances in the range 2.51-2.60 Å, resulting in a tight head-to-tail packing.

No MeSH data available.