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Triaqua-(cyclo-hex-4-ene-1,2-dicarboxyl-ato-κO(1))(1,10-phenanthroline-κ(2)N,N')cobalt(II).

Li HY, Wang C, Huang FP, Jiang YM - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry.The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H⋯O hydrogen-bonding inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.784 (3) Å], forming a three-dimensional supra-molecular network.

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Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China.

ABSTRACT
In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry. The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H⋯O hydrogen-bonding inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.784 (3) Å], forming a three-dimensional supra-molecular network.

No MeSH data available.


A packing diagram of the title compound. Hydrogen bonds are shown as dotted lines.
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Fap2: A packing diagram of the title compound. Hydrogen bonds are shown as dotted lines.


Triaqua-(cyclo-hex-4-ene-1,2-dicarboxyl-ato-κO(1))(1,10-phenanthroline-κ(2)N,N')cobalt(II).

Li HY, Wang C, Huang FP, Jiang YM - Acta Crystallogr Sect E Struct Rep Online (2012)

A packing diagram of the title compound. Hydrogen bonds are shown as dotted lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515127&req=5

Fap2: A packing diagram of the title compound. Hydrogen bonds are shown as dotted lines.
Bottom Line: In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry.The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H⋯O hydrogen-bonding inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.784 (3) Å], forming a three-dimensional supra-molecular network.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China.

ABSTRACT
In the title compound, [Co(C(8)H(8)O(4))(C(12)H(8)N(2))(H(2)O)(3)], the Co(II) atom is coordinated by two N atoms from a bidentate 1,10-phenanthroline ligand, one O atom from a monodentate 4-cyclo-hexene-1,2-dicarboxyl-ate ligand and three water O atoms in a distorted octa-hedral geometry. The mononuclear mol-ecules are engaged in extensive intra- and inter-molecular O-H⋯O hydrogen-bonding inter-actions and π-π stacking inter-actions [centroid-centroid distance = 3.784 (3) Å], forming a three-dimensional supra-molecular network.

No MeSH data available.