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μ-(2,2'-Bipyrimidine)-bis-[dichlorido-palladium(II)] dimethyl-formamide monosolvate.

Young C, Roodt A, Bezuidenhoudt BC - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand.Two terminal chloride anions are also bonded to each of the Pd(2+) cations.The C and O atoms of the solvent mol-ecule are disordered over two sets of sites of equal occupancy.

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Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein, 9300, South Africa.

ABSTRACT
In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter-section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol-ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol-ecule are disordered over two sets of sites of equal occupancy.

No MeSH data available.


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Diamond representation of the title compound, showing the numbering scheme and displacement ellipsoids (50% probability).
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Fap1: Diamond representation of the title compound, showing the numbering scheme and displacement ellipsoids (50% probability).


μ-(2,2'-Bipyrimidine)-bis-[dichlorido-palladium(II)] dimethyl-formamide monosolvate.

Young C, Roodt A, Bezuidenhoudt BC - Acta Crystallogr Sect E Struct Rep Online (2012)

Diamond representation of the title compound, showing the numbering scheme and displacement ellipsoids (50% probability).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515126&req=5

Fap1: Diamond representation of the title compound, showing the numbering scheme and displacement ellipsoids (50% probability).
Bottom Line: In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand.Two terminal chloride anions are also bonded to each of the Pd(2+) cations.The C and O atoms of the solvent mol-ecule are disordered over two sets of sites of equal occupancy.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein, 9300, South Africa.

ABSTRACT
In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter-section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol-ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol-ecule are disordered over two sets of sites of equal occupancy.

No MeSH data available.


Related in: MedlinePlus