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Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II).

Bungu PS, Schutte M, Steyl G - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry.Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis.The mol-ecules pack in layers along the diagonal of the bc plane.

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Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Nelson Mandela Drive, Bloemfontein 9301, South Africa.

ABSTRACT
In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis. The mol-ecules pack in layers along the diagonal of the bc plane.

No MeSH data available.


Related in: MedlinePlus

Observed hydrogen interactions (green dashed line), π-π stacking (yellow dashed lines) and π-interactions(red dashed lines) in the crystal structure (hydrogen atoms omitted for clarity).
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Fap2: Observed hydrogen interactions (green dashed line), π-π stacking (yellow dashed lines) and π-interactions(red dashed lines) in the crystal structure (hydrogen atoms omitted for clarity).


Bis[4-(4-bromophenylimino-κN)pent-2-en-2-olato-κO]copper(II).

Bungu PS, Schutte M, Steyl G - Acta Crystallogr Sect E Struct Rep Online (2012)

Observed hydrogen interactions (green dashed line), π-π stacking (yellow dashed lines) and π-interactions(red dashed lines) in the crystal structure (hydrogen atoms omitted for clarity).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515125&req=5

Fap2: Observed hydrogen interactions (green dashed line), π-π stacking (yellow dashed lines) and π-interactions(red dashed lines) in the crystal structure (hydrogen atoms omitted for clarity).
Bottom Line: In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry.Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis.The mol-ecules pack in layers along the diagonal of the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of the Free State, PO Box 339, Nelson Mandela Drive, Bloemfontein 9301, South Africa.

ABSTRACT
In the title compound, [Cu(C(11)H(11)BrNO)(2)], the Cu(II) atom is in a distorted square-planar geometry, with the two bidentate ketimine ligands positioned in a trans geometry. Two inter-molecular C-H⋯O hydrogen bond inter-actions are present which link the mol-ecules in a zigzag manner along the a axis. The mol-ecules pack in layers along the diagonal of the bc plane.

No MeSH data available.


Related in: MedlinePlus