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Sodium penta-fluoro-phenyl-borate.

Vitze H, Lerner HW, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations.The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network.The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

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Affiliation: Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von-Laue-Str. 7, 60438 Frankfurt/Main, Germany.

ABSTRACT
The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

No MeSH data available.


Reaction scheme for obtaining the title compound.
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Fap1: Reaction scheme for obtaining the title compound.


Sodium penta-fluoro-phenyl-borate.

Vitze H, Lerner HW, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Reaction scheme for obtaining the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515123&req=5

Fap1: Reaction scheme for obtaining the title compound.
Bottom Line: The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations.The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network.The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von-Laue-Str. 7, 60438 Frankfurt/Main, Germany.

ABSTRACT
The crystal structure of the title compound, Na[(C(6)F(5))BH(3)], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na⋯B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na⋯F contacts [2.348 (5) and 2.392 (5) Å], forming a three-dimensional network. The anion is the first structural example of a pentafluorophenyl ring carrying a BH(3) group.

No MeSH data available.