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Poly[di-μ(3)-hy-droxy[μ(4)-5-(4-carb-oxy-phen-yl)pyridine-2-carboxyl-ato-κ(5)N,O(2):O(2'):O(4):O(4')]dicadmium].

Meng FJ, Jia HQ, Hu NH, Zhou H - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: One Cd(II) atom is six-coordinated by two O atoms from two ligand mol-ecules and by four μ(3)-OH groups in a distorted trigonal-prismatic geometry.The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry.The two independent Cd(II) atoms are connected by the ligand mol-ecules and the OH groups into a three-dimensional framework.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.

ABSTRACT
The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb-oxy-phen-yl)pyridine-2-carboxyl-ate ligand and two hy-droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol-ecules and by four μ(3)-OH groups in a distorted trigonal-prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand mol-ecules and the OH groups into a three-dimensional framework. O-H⋯O hydrogen bonds between the OH groups and the carboxyl-ate O atoms are observed.

No MeSH data available.


The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) x, -1+y, z; (ii) 1-x, -1/2+y, 1/2-z; (iii) 1-x, 2-y, 1-z; (iv) 2-x, 1-y, 1-z; (v) x, 1+y, z.]
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Fap1: The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) x, -1+y, z; (ii) 1-x, -1/2+y, 1/2-z; (iii) 1-x, 2-y, 1-z; (iv) 2-x, 1-y, 1-z; (v) x, 1+y, z.]


Poly[di-μ(3)-hy-droxy[μ(4)-5-(4-carb-oxy-phen-yl)pyridine-2-carboxyl-ato-κ(5)N,O(2):O(2'):O(4):O(4')]dicadmium].

Meng FJ, Jia HQ, Hu NH, Zhou H - Acta Crystallogr Sect E Struct Rep Online (2012)

The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) x, -1+y, z; (ii) 1-x, -1/2+y, 1/2-z; (iii) 1-x, 2-y, 1-z; (iv) 2-x, 1-y, 1-z; (v) x, 1+y, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515118&req=5

Fap1: The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) x, -1+y, z; (ii) 1-x, -1/2+y, 1/2-z; (iii) 1-x, 2-y, 1-z; (iv) 2-x, 1-y, 1-z; (v) x, 1+y, z.]
Bottom Line: One Cd(II) atom is six-coordinated by two O atoms from two ligand mol-ecules and by four μ(3)-OH groups in a distorted trigonal-prismatic geometry.The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry.The two independent Cd(II) atoms are connected by the ligand mol-ecules and the OH groups into a three-dimensional framework.

View Article: PubMed Central - HTML - PubMed

Affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China.

ABSTRACT
The asymmetric unit of the title polymeric complex, [Cd(2)(C(13)H(7)NO(4))(OH)(2)](n), consists of two independent Cd(II) atoms, one 5-(4-carb-oxy-phen-yl)pyridine-2-carboxyl-ate ligand and two hy-droxy groups. One Cd(II) atom is six-coordinated by two O atoms from two ligand mol-ecules and by four μ(3)-OH groups in a distorted trigonal-prismatic geometry. The other is five-coordinated by one N and two O atoms from two ligands and by two μ(3)-OH groups, forming a distorted square-pyramidal geometry. The two independent Cd(II) atoms are connected by the ligand mol-ecules and the OH groups into a three-dimensional framework. O-H⋯O hydrogen bonds between the OH groups and the carboxyl-ate O atoms are observed.

No MeSH data available.