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Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

Shirvan SA, Haydari Dezfuli S, Khazali F, Aghajeri M, Borsalani A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms.Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine rings in the bc plane [centroid-centroid distance = 3.725 (3) Å] are present in the crystal structure.

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Affiliation: Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.

ABSTRACT
In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms. Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine rings in the bc plane [centroid-centroid distance = 3.725 (3) Å] are present in the crystal structure.

No MeSH data available.


The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.


Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

Shirvan SA, Haydari Dezfuli S, Khazali F, Aghajeri M, Borsalani A - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515117&req=5

Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms.Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine rings in the bc plane [centroid-centroid distance = 3.725 (3) Å] are present in the crystal structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.

ABSTRACT
In the title compound, [CoBr(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and by two terminal Br atoms. Inter-molecular C-H⋯Br hydrogen bonds and π-π stacking between the pyridine rings in the bc plane [centroid-centroid distance = 3.725 (3) Å] are present in the crystal structure.

No MeSH data available.