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Bis(2,2'-bipyrimidine-κ(2)N(1),N(1'))palladium(II) bis-(tetra-fluoro-borate) acetonitrile monosolvate.

Duong A, Wuest JD, Maris T - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Each metal atom adopts a tetra-hedrally distorted square-planar geometry.The chains are further linked by C-H⋯F and C-H⋯N inter-actions involving the tetra-fluoro-borate anions and acetonitrile mol-ecules.In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Département de Chimie, Université de Montréal, 2900 Boulevard Édouard-Montpetit, Montréal, Québec, Canada H3C 3J7.

ABSTRACT
The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2'-bipyrimidine (bpm) in MeCN-CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra-hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C-H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C-H⋯F and C-H⋯N inter-actions involving the tetra-fluoro-borate anions and acetonitrile mol-ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

No MeSH data available.


Related in: MedlinePlus

View along the b-axis of the unit-cell content. C—H···N and C—H···F contacts are shown as dashed lines.
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Fap3: View along the b-axis of the unit-cell content. C—H···N and C—H···F contacts are shown as dashed lines.


Bis(2,2'-bipyrimidine-κ(2)N(1),N(1'))palladium(II) bis-(tetra-fluoro-borate) acetonitrile monosolvate.

Duong A, Wuest JD, Maris T - Acta Crystallogr Sect E Struct Rep Online (2012)

View along the b-axis of the unit-cell content. C—H···N and C—H···F contacts are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515108&req=5

Fap3: View along the b-axis of the unit-cell content. C—H···N and C—H···F contacts are shown as dashed lines.
Bottom Line: Each metal atom adopts a tetra-hedrally distorted square-planar geometry.The chains are further linked by C-H⋯F and C-H⋯N inter-actions involving the tetra-fluoro-borate anions and acetonitrile mol-ecules.In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Département de Chimie, Université de Montréal, 2900 Boulevard Édouard-Montpetit, Montréal, Québec, Canada H3C 3J7.

ABSTRACT
The reaction of [Pd(MeCN)(4)](BF(4))(2) with 2,2'-bipyrimidine (bpm) in MeCN-CHCl(3) afforded the title compound, [Pd(C(8)H(6)N(4))(2)](BF(4))(2)·C(2)H(3)N. The asymmetric unit contains two half complexes, with the Pd(II) atoms both lying on a twofold axis. Each metal atom adopts a tetra-hedrally distorted square-planar geometry. In the crystal, [Pd(bpm)(2)] dications are linked by C-H⋯N hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by C-H⋯F and C-H⋯N inter-actions involving the tetra-fluoro-borate anions and acetonitrile mol-ecules. In this way, each chain interacts with six surrounding chains to generate the observed three-dimensional structure.

No MeSH data available.


Related in: MedlinePlus