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Tetra-kis(μ-acetato-κ(2)O:O')-bis-[(3-pyridine-carboxaldehyde-κN')]dicopper(II)(Cu-Cu).

Cruz-Enriquez A, Baez-Castro A, Höpfl H, Parra-Hake M, Campos-Gaxiola JJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion.The Cu(II) atoms are connected [Cu-Cu = 2.6134 (5) Å] and bridged by four acetate ligands.Their distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand.

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Affiliation: Facultad de Ingenieria Mochis, Universidad Autonoma de Sinaloa, Fuente Poseidon y Prol. A. Flores S/N, CP 81223, C.U. Los Mochis, Sinaloa, Mexico.

ABSTRACT
The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu-Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex mol-ecules are linked by C-H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C-H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supra-molecular architecture.

No MeSH data available.


Perspective view of a fragment of the two-dimensional supramolecular network with the C—H···O hydrogen bonds shown as dashed lines.
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Fap2: Perspective view of a fragment of the two-dimensional supramolecular network with the C—H···O hydrogen bonds shown as dashed lines.


Tetra-kis(μ-acetato-κ(2)O:O')-bis-[(3-pyridine-carboxaldehyde-κN')]dicopper(II)(Cu-Cu).

Cruz-Enriquez A, Baez-Castro A, Höpfl H, Parra-Hake M, Campos-Gaxiola JJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Perspective view of a fragment of the two-dimensional supramolecular network with the C—H···O hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515103&req=5

Fap2: Perspective view of a fragment of the two-dimensional supramolecular network with the C—H···O hydrogen bonds shown as dashed lines.
Bottom Line: The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion.The Cu(II) atoms are connected [Cu-Cu = 2.6134 (5) Å] and bridged by four acetate ligands.Their distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand.

View Article: PubMed Central - HTML - PubMed

Affiliation: Facultad de Ingenieria Mochis, Universidad Autonoma de Sinaloa, Fuente Poseidon y Prol. A. Flores S/N, CP 81223, C.U. Los Mochis, Sinaloa, Mexico.

ABSTRACT
The binuclear title compound, [Cu(2)(CH(3)CO(2))(4)(C(6)H(5)NO)], is located about a center of inversion. The Cu(II) atoms are connected [Cu-Cu = 2.6134 (5) Å] and bridged by four acetate ligands. Their distorted octa-hedral coordination geometry is completed by a terminal pyridine N atom of a 3-pyridincarboxaldehyde ligand. In the crystal, the complex mol-ecules are linked by C-H⋯O hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane. These networks are linked via C-H⋯O hydrogen bonds involving inversion-related 3-pyridinecarboxaldehyde ligands, forming a three dimensional supra-molecular architecture.

No MeSH data available.