Limits...
μ(2)-Oxalato-bis-[triphen-yl(thio-urea-κS)tin(IV)].

Sow Y, Diop L, Molloy KC, Kociok-Kohn G - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol-ecule.The Sn(IV) atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio-urea and the monodentately bridging oxalate anion in axial positions.Weak C-H⋯O inter-actions are also present.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Minerale et Analytique (LACHIMIA), Departement de Chimie, Faculte des Sciences et Techniques, Universite Cheikh, Anta Diop Dakar Senegal.

ABSTRACT
The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol-ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn(IV) atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio-urea and the monodentately bridging oxalate anion in axial positions. The mol-ecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thio-urea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O inter-actions are also present.

No MeSH data available.


Related in: MedlinePlus

The molecule of the title complex showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry code a) -x, y, -z + 1/2.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3515101&req=5

Fap1: The molecule of the title complex showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry code a) -x, y, -z + 1/2.]


μ(2)-Oxalato-bis-[triphen-yl(thio-urea-κS)tin(IV)].

Sow Y, Diop L, Molloy KC, Kociok-Kohn G - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecule of the title complex showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry code a) -x, y, -z + 1/2.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515101&req=5

Fap1: The molecule of the title complex showing the numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry code a) -x, y, -z + 1/2.]
Bottom Line: The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol-ecule.The Sn(IV) atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio-urea and the monodentately bridging oxalate anion in axial positions.Weak C-H⋯O inter-actions are also present.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Chimie Minerale et Analytique (LACHIMIA), Departement de Chimie, Faculte des Sciences et Techniques, Universite Cheikh, Anta Diop Dakar Senegal.

ABSTRACT
The asymmetric unit of the binuclear title compound, [Sn(2)(C(2)O(4))(C(6)H(5))(6)(CH(4)N(2)S)(2)], consists of one half of the organotin(IV) mol-ecule. The remainder is generated by a twofold rotation axis passing through the mid-point of the oxalate C-C bond. The Sn(IV) atom exhibits a distorted trigonal-bipyramidal coordination environment with the phenyl groups in equatorial positions and the thio-urea and the monodentately bridging oxalate anion in axial positions. The mol-ecules are linked through N-H⋯O hydrogen bonds involving the amino group of the thio-urea ligand and the uncoordinating oxalate O atoms, forming layers parallel to (001). Weak C-H⋯O inter-actions are also present.

No MeSH data available.


Related in: MedlinePlus