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Trichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')(dimethyl-sulfoxide-κO)indium(III).

Shirvan SA, Haydari Dezfuli S, Golabi E, Gholamzadeh MA - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [In(C(11)H(10)N(2))Cl(3)(C(2)H(6)OS)], the In(III) cation is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl-sulfoxide group and three Cl(-) anions.Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and intra-molecular C-H⋯Cl hydrogen bonds are present in the structure.

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Affiliation: Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.

ABSTRACT
In the title compound, [In(C(11)H(10)N(2))Cl(3)(C(2)H(6)OS)], the In(III) cation is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl-sulfoxide group and three Cl(-) anions. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and intra-molecular C-H⋯Cl hydrogen bonds are present in the structure.

No MeSH data available.


The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
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Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.


Trichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')(dimethyl-sulfoxide-κO)indium(III).

Shirvan SA, Haydari Dezfuli S, Golabi E, Gholamzadeh MA - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515094&req=5

Fap1: The molecular structure of the title molecule, with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
Bottom Line: In the title compound, [In(C(11)H(10)N(2))Cl(3)(C(2)H(6)OS)], the In(III) cation is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl-sulfoxide group and three Cl(-) anions.Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and intra-molecular C-H⋯Cl hydrogen bonds are present in the structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.

ABSTRACT
In the title compound, [In(C(11)H(10)N(2))Cl(3)(C(2)H(6)OS)], the In(III) cation is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 6-methyl-2,2'-bipyridine ligand, one O atom from a dimethyl-sulfoxide group and three Cl(-) anions. Weak inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds and intra-molecular C-H⋯Cl hydrogen bonds are present in the structure.

No MeSH data available.