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N,N'-bis-[(3-hy-droxy-4(4H)-oxypyran-2-yl)meth-yl]-N,N'-dimethyl-ethylene-1,2-diammonium tetra-chloridoplatinate(II) dihydrate.

Fusi V, Giorgi L, Macedi E, Paoli P, Rossi P - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit consists of one solvent water mol-ecule on a general position, and one half of each of the polyammonium cation and the tetrachloridoplatinate(II) anion, both of them located on centers of inversion.In addition, the carbonyl O atom is hydrogen-bonded to the water mol-ecule which, in turn, inter-acts with the [PtCl(4)](2-) anion.Finally, the chains are linked by N-H(+)⋯Cl inter-actions into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Basic Sciences and Fundamentals, University of Urbino, I-61029 Urbino, Italy.

ABSTRACT
The title compound (C(16)H(22)N(2)O(6))[PtCl(4)]·2H(2)O, shows anti-proliferative activity in eight tumor cell lines. The asymmetric unit consists of one solvent water mol-ecule on a general position, and one half of each of the polyammonium cation and the tetrachloridoplatinate(II) anion, both of them located on centers of inversion. In the crystal, the cations are connected via hydrogen bonding between the carbonyl O atoms and the hydroxyl H atoms into zigzag chains that elongate in the c-axis direction. In addition, the carbonyl O atom is hydrogen-bonded to the water mol-ecule which, in turn, inter-acts with the [PtCl(4)](2-) anion. Finally, the chains are linked by N-H(+)⋯Cl inter-actions into a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus

Crystal structure of the title compound with view along the a axis. Intermolecular hydrogen bonding is shown as dashed lines.
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Fap2: Crystal structure of the title compound with view along the a axis. Intermolecular hydrogen bonding is shown as dashed lines.


N,N'-bis-[(3-hy-droxy-4(4H)-oxypyran-2-yl)meth-yl]-N,N'-dimethyl-ethylene-1,2-diammonium tetra-chloridoplatinate(II) dihydrate.

Fusi V, Giorgi L, Macedi E, Paoli P, Rossi P - Acta Crystallogr Sect E Struct Rep Online (2012)

Crystal structure of the title compound with view along the a axis. Intermolecular hydrogen bonding is shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515092&req=5

Fap2: Crystal structure of the title compound with view along the a axis. Intermolecular hydrogen bonding is shown as dashed lines.
Bottom Line: The asymmetric unit consists of one solvent water mol-ecule on a general position, and one half of each of the polyammonium cation and the tetrachloridoplatinate(II) anion, both of them located on centers of inversion.In addition, the carbonyl O atom is hydrogen-bonded to the water mol-ecule which, in turn, inter-acts with the [PtCl(4)](2-) anion.Finally, the chains are linked by N-H(+)⋯Cl inter-actions into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Basic Sciences and Fundamentals, University of Urbino, I-61029 Urbino, Italy.

ABSTRACT
The title compound (C(16)H(22)N(2)O(6))[PtCl(4)]·2H(2)O, shows anti-proliferative activity in eight tumor cell lines. The asymmetric unit consists of one solvent water mol-ecule on a general position, and one half of each of the polyammonium cation and the tetrachloridoplatinate(II) anion, both of them located on centers of inversion. In the crystal, the cations are connected via hydrogen bonding between the carbonyl O atoms and the hydroxyl H atoms into zigzag chains that elongate in the c-axis direction. In addition, the carbonyl O atom is hydrogen-bonded to the water mol-ecule which, in turn, inter-acts with the [PtCl(4)](2-) anion. Finally, the chains are linked by N-H(+)⋯Cl inter-actions into a three-dimensional network.

No MeSH data available.


Related in: MedlinePlus