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Tetra-amminelithium triamminelithium tris-ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)].

Guentner C, Korber N - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The anions contain LiSN(3) tetra-hedra; the S-S-S bond angles are 110.43 (5) and 109.53 (5)°.In the crystal, the components are linked by multiple N-H⋯S hydrogen bonds.A weak N-H⋯N hydrogen bond is also present.

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Affiliation: Institut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
The title compound, [Li(NH(3))(4)](+)[Li(NH(3))(3)S(3)](-), an ammo-niate of the previously unknown lithium tris-ulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH(3))(4)](+) cations are close to regular LiN(4) tetra-hedra. The anions contain LiSN(3) tetra-hedra; the S-S-S bond angles are 110.43 (5) and 109.53 (5)°. In the crystal, the components are linked by multiple N-H⋯S hydrogen bonds. A weak N-H⋯N hydrogen bond is also present.

No MeSH data available.


Asymmetric unit of [Li(NH3)4][Li(NH3)3S3]. Ellipsoids of all non-hydrogen atoms are given with a probability level of 50%.
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Fap1: Asymmetric unit of [Li(NH3)4][Li(NH3)3S3]. Ellipsoids of all non-hydrogen atoms are given with a probability level of 50%.


Tetra-amminelithium triamminelithium tris-ulfide, [Li(NH(3))(4)][Li(NH(3))(3)S(3)].

Guentner C, Korber N - Acta Crystallogr Sect E Struct Rep Online (2012)

Asymmetric unit of [Li(NH3)4][Li(NH3)3S3]. Ellipsoids of all non-hydrogen atoms are given with a probability level of 50%.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515087&req=5

Fap1: Asymmetric unit of [Li(NH3)4][Li(NH3)3S3]. Ellipsoids of all non-hydrogen atoms are given with a probability level of 50%.
Bottom Line: The anions contain LiSN(3) tetra-hedra; the S-S-S bond angles are 110.43 (5) and 109.53 (5)°.In the crystal, the components are linked by multiple N-H⋯S hydrogen bonds.A weak N-H⋯N hydrogen bond is also present.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, Germany.

ABSTRACT
The title compound, [Li(NH(3))(4)](+)[Li(NH(3))(3)S(3)](-), an ammo-niate of the previously unknown lithium tris-ulfide, was obtained from the reaction of lithium and sulfur in liquid ammonia. The asymmetric unit consists of two crystallographically independent formula units. The [Li(NH(3))(4)](+) cations are close to regular LiN(4) tetra-hedra. The anions contain LiSN(3) tetra-hedra; the S-S-S bond angles are 110.43 (5) and 109.53 (5)°. In the crystal, the components are linked by multiple N-H⋯S hydrogen bonds. A weak N-H⋯N hydrogen bond is also present.

No MeSH data available.