Limits...
LiNa(5)Mo(9)O(30).

Hamza H, Ennajeh I, Zid MF, Driss A - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The three-dimensional [Mo(9)O(30)](6-) framework is built up from MoO(6) octa-hedra and MoO(5) bipyramids, linked together by edges and corners.The framework delimits two types of inter-secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located.Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis, Tunisia.

ABSTRACT
The tite compound, lithium penta-sodium nona-molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6-) framework is built up from MoO(6) octa-hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of inter-secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located. The asymmetric unit contains one Mo, one Na and one Li site located on a twofold rotation axis. The crystal studied was a racemic twin with site a twin ratio of 0.51 (10):0.49 (10). Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed.

No MeSH data available.


Related in: MedlinePlus

Projection de la structure de LiNa5Mo9O30, selon la direction [010], montrant l'emplacement des cations monovalents.
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Fap4: Projection de la structure de LiNa5Mo9O30, selon la direction [010], montrant l'emplacement des cations monovalents.


LiNa(5)Mo(9)O(30).

Hamza H, Ennajeh I, Zid MF, Driss A - Acta Crystallogr Sect E Struct Rep Online (2012)

Projection de la structure de LiNa5Mo9O30, selon la direction [010], montrant l'emplacement des cations monovalents.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3515084&req=5

Fap4: Projection de la structure de LiNa5Mo9O30, selon la direction [010], montrant l'emplacement des cations monovalents.
Bottom Line: The three-dimensional [Mo(9)O(30)](6-) framework is built up from MoO(6) octa-hedra and MoO(5) bipyramids, linked together by edges and corners.The framework delimits two types of inter-secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located.Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis, Tunisia.

ABSTRACT
The tite compound, lithium penta-sodium nona-molybdate, LiNa(5)Mo(9)O(30), was synthesized by solid-state reaction. The three-dimensional [Mo(9)O(30)](6-) framework is built up from MoO(6) octa-hedra and MoO(5) bipyramids, linked together by edges and corners. The framework delimits two types of inter-secting tunnels running along [100] and [010] in which the Na(+) and Li(+) ions are located. The asymmetric unit contains one Mo, one Na and one Li site located on a twofold rotation axis. The crystal studied was a racemic twin with site a twin ratio of 0.51 (10):0.49 (10). Relationships between the structures of K(2)Mo(3)O(10), K(2)Mo(4)O(13), Cs(2)Mo(7)O(22), Na(6)Mo(10)O(33) and Na(6)Mo(11)O(36) compounds are discussed.

No MeSH data available.


Related in: MedlinePlus