Limits...
3,3'-Dicyclo-pentyl-1,1'-(1,3-phenyl-enedimethyl-ene)dibenzimidazol-1-ium bis-(hexa-fluoro-phosphate).

Haque RA, Nasri SF, Rosli MM, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, C(32)H(36)N(4) (2+)·2PF(6) (-), the cation and the anions each have crystallographic twofold rotation symmetry.The benzimidazole ring is almost planar [r.m.s. deviation = 0.0161 (1) Å] and makes a dihedral angle of 5.77 (4)° with its symmetry-related component and a dihedral angle of 80.96 (5)° with the central benzene ring.The cyclo-pentyl ring adopts a half-chair conformation.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(32)H(36)N(4) (2+)·2PF(6) (-), the cation and the anions each have crystallographic twofold rotation symmetry. The benzimidazole ring is almost planar [r.m.s. deviation = 0.0161 (1) Å] and makes a dihedral angle of 5.77 (4)° with its symmetry-related component and a dihedral angle of 80.96 (5)° with the central benzene ring. The cyclo-pentyl ring adopts a half-chair conformation. In the crystal, mol-ecules are linked into a three-dimensional network through C-H⋯F hydrogen bonds. A C-H⋯π inter-action is also observed.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound, showing 50% probability displacement ellipsoids. Hydrogen atoms are shown as spheres of arbitrary radius. Atoms with suffix A, B and C are generated by the symmetry operators (-x, y, 1/2-z), (x, -y, 1-z) and (-x, y, 3/2-z), respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379432&req=5

Fap1: The molecular structure of the title compound, showing 50% probability displacement ellipsoids. Hydrogen atoms are shown as spheres of arbitrary radius. Atoms with suffix A, B and C are generated by the symmetry operators (-x, y, 1/2-z), (x, -y, 1-z) and (-x, y, 3/2-z), respectively.


3,3'-Dicyclo-pentyl-1,1'-(1,3-phenyl-enedimethyl-ene)dibenzimidazol-1-ium bis-(hexa-fluoro-phosphate).

Haque RA, Nasri SF, Rosli MM, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound, showing 50% probability displacement ellipsoids. Hydrogen atoms are shown as spheres of arbitrary radius. Atoms with suffix A, B and C are generated by the symmetry operators (-x, y, 1/2-z), (x, -y, 1-z) and (-x, y, 3/2-z), respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379432&req=5

Fap1: The molecular structure of the title compound, showing 50% probability displacement ellipsoids. Hydrogen atoms are shown as spheres of arbitrary radius. Atoms with suffix A, B and C are generated by the symmetry operators (-x, y, 1/2-z), (x, -y, 1-z) and (-x, y, 3/2-z), respectively.
Bottom Line: In the title compound, C(32)H(36)N(4) (2+)·2PF(6) (-), the cation and the anions each have crystallographic twofold rotation symmetry.The benzimidazole ring is almost planar [r.m.s. deviation = 0.0161 (1) Å] and makes a dihedral angle of 5.77 (4)° with its symmetry-related component and a dihedral angle of 80.96 (5)° with the central benzene ring.The cyclo-pentyl ring adopts a half-chair conformation.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(32)H(36)N(4) (2+)·2PF(6) (-), the cation and the anions each have crystallographic twofold rotation symmetry. The benzimidazole ring is almost planar [r.m.s. deviation = 0.0161 (1) Å] and makes a dihedral angle of 5.77 (4)° with its symmetry-related component and a dihedral angle of 80.96 (5)° with the central benzene ring. The cyclo-pentyl ring adopts a half-chair conformation. In the crystal, mol-ecules are linked into a three-dimensional network through C-H⋯F hydrogen bonds. A C-H⋯π inter-action is also observed.

No MeSH data available.


Related in: MedlinePlus