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4-[(E)-2-(2-Chloro-benzyl-idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate.

Tiekink ER, Wardell SM, Wardell JL, Ferreira Mde L, de Souza MV, Kaiser CR - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(-)·2H(2)O, a small twist is evident in the cation so that the chloro-benzene ring is not coplanar with the central hydrazinyl group [the N-C-C-C torsion angle = -4.8 (12)°].The conformation about the imine N=C bond [1.284 (10) Å] is E.One water H atom is disposed over two sites of equal occupancy.

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ABSTRACT
In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(-)·2H(2)O, a small twist is evident in the cation so that the chloro-benzene ring is not coplanar with the central hydrazinyl group [the N-C-C-C torsion angle = -4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy.

No MeSH data available.


Related in: MedlinePlus

The molecular structure showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Only one position of the disordered H atoms of the O2w water molecule is shown.
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Fap1: The molecular structure showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Only one position of the disordered H atoms of the O2w water molecule is shown.


4-[(E)-2-(2-Chloro-benzyl-idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate.

Tiekink ER, Wardell SM, Wardell JL, Ferreira Mde L, de Souza MV, Kaiser CR - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Only one position of the disordered H atoms of the O2w water molecule is shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379418&req=5

Fap1: The molecular structure showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. Only one position of the disordered H atoms of the O2w water molecule is shown.
Bottom Line: In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(-)·2H(2)O, a small twist is evident in the cation so that the chloro-benzene ring is not coplanar with the central hydrazinyl group [the N-C-C-C torsion angle = -4.8 (12)°].The conformation about the imine N=C bond [1.284 (10) Å] is E.One water H atom is disposed over two sites of equal occupancy.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(-)·2H(2)O, a small twist is evident in the cation so that the chloro-benzene ring is not coplanar with the central hydrazinyl group [the N-C-C-C torsion angle = -4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy.

No MeSH data available.


Related in: MedlinePlus