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2-Amino-N'-phenyl-benzohydrazide.

Kesternich V, Gahona P, Pérez-Fehrmann M, Brito I, López-Rodríguez M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively.The dihedral angles between the aromatic rings is 61.2 (1)°.The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].

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ABSTRACT
In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N-H⋯N hydrogen bonds, forming R(4) (4)(20) rings, and resulting in the formation of a two-dimensional network lying parallel to (010). The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].

No MeSH data available.


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A partial view along the c axis of the crystal packing of the title compound, showing the formation of the N—H··· O hydrogen bonded chain and the centrosymmetric R44 (20) rings [see Table 1 for details; the H-atoms not involved in hydrogen-bonding have been omitted for clarity]
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Fap2: A partial view along the c axis of the crystal packing of the title compound, showing the formation of the N—H··· O hydrogen bonded chain and the centrosymmetric R44 (20) rings [see Table 1 for details; the H-atoms not involved in hydrogen-bonding have been omitted for clarity]


2-Amino-N'-phenyl-benzohydrazide.

Kesternich V, Gahona P, Pérez-Fehrmann M, Brito I, López-Rodríguez M - Acta Crystallogr Sect E Struct Rep Online (2012)

A partial view along the c axis of the crystal packing of the title compound, showing the formation of the N—H··· O hydrogen bonded chain and the centrosymmetric R44 (20) rings [see Table 1 for details; the H-atoms not involved in hydrogen-bonding have been omitted for clarity]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379416&req=5

Fap2: A partial view along the c axis of the crystal packing of the title compound, showing the formation of the N—H··· O hydrogen bonded chain and the centrosymmetric R44 (20) rings [see Table 1 for details; the H-atoms not involved in hydrogen-bonding have been omitted for clarity]
Bottom Line: In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively.The dihedral angles between the aromatic rings is 61.2 (1)°.The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(13)H(13)N(3)O, the NNCO unit forms dihedral angles of 35.8 (1) and 84.0 (1)° with the benzene and phenyl rings, respectively. The dihedral angles between the aromatic rings is 61.2 (1)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds into C(4) chains parallel to the c axis. Neighbouring chains are linked by weak N-H⋯N hydrogen bonds, forming R(4) (4)(20) rings, and resulting in the formation of a two-dimensional network lying parallel to (010). The packing also features π-π stacking inter-actions between phenyl rings [centroid-centroid distance = 3.803 (2) Å].

No MeSH data available.


Related in: MedlinePlus