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4-[(E)-({4-[(4-Amino-phen-yl)sulfon-yl]phen-yl}imino)-meth-yl]phenol ethanol monosolvate.

Afzal S, Akhter Z, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups.The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups.There also exist π-π inter-actions with a distance of 3.5976 (18) Å between the centroids of hy-droxy-phenyl rings.

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ABSTRACT
In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups. The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups. In the crystal, a two-dimensional polymeric network parallel to (010) is formed by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds. There also exist π-π inter-actions with a distance of 3.5976 (18) Å between the centroids of hy-droxy-phenyl rings.

No MeSH data available.


The partial packing (PLATON; Spek, 2009) which shows that molecules form two dimensional polymeric network. The H-atoms not involved in H-bondings are omitted for clarity.
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Fap2: The partial packing (PLATON; Spek, 2009) which shows that molecules form two dimensional polymeric network. The H-atoms not involved in H-bondings are omitted for clarity.


4-[(E)-({4-[(4-Amino-phen-yl)sulfon-yl]phen-yl}imino)-meth-yl]phenol ethanol monosolvate.

Afzal S, Akhter Z, Tahir MN - Acta Crystallogr Sect E Struct Rep Online (2012)

The partial packing (PLATON; Spek, 2009) which shows that molecules form two dimensional polymeric network. The H-atoms not involved in H-bondings are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379368&req=5

Fap2: The partial packing (PLATON; Spek, 2009) which shows that molecules form two dimensional polymeric network. The H-atoms not involved in H-bondings are omitted for clarity.
Bottom Line: In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups.The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups.There also exist π-π inter-actions with a distance of 3.5976 (18) Å between the centroids of hy-droxy-phenyl rings.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups. The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups. In the crystal, a two-dimensional polymeric network parallel to (010) is formed by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds. There also exist π-π inter-actions with a distance of 3.5976 (18) Å between the centroids of hy-droxy-phenyl rings.

No MeSH data available.