Limits...
O-Propyl N-phenyl-thio-carbamate.

Sudkaow P, Yeo CI, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS.These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95 (13) and 55.92 (13)°, respectively].The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20 (12) and -144.15 (12)°, respectively; q = quaternary and ph = phen-yl].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20 (12) and -144.15 (12)°, respectively; q = quaternary and ph = phen-yl]. The independent mol-ecules are linked into a dimeric aggregate by N-H⋯S hydrogen bonds and an eight-membered thio-amide {⋯H-N-C=S}(2) synthon.

No MeSH data available.


Related in: MedlinePlus

Overlay diagram of the two independent molecules comprising the asymmetric unit of (I). The first independent molecule (with the S1 atom) is shown in red and the second (S2) in blue. The S, O and N atoms in each molecule have been overlapped.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379354&req=5

Fap2: Overlay diagram of the two independent molecules comprising the asymmetric unit of (I). The first independent molecule (with the S1 atom) is shown in red and the second (S2) in blue. The S, O and N atoms in each molecule have been overlapped.


O-Propyl N-phenyl-thio-carbamate.

Sudkaow P, Yeo CI, Ng SW, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Overlay diagram of the two independent molecules comprising the asymmetric unit of (I). The first independent molecule (with the S1 atom) is shown in red and the second (S2) in blue. The S, O and N atoms in each molecule have been overlapped.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379354&req=5

Fap2: Overlay diagram of the two independent molecules comprising the asymmetric unit of (I). The first independent molecule (with the S1 atom) is shown in red and the second (S2) in blue. The S, O and N atoms in each molecule have been overlapped.
Bottom Line: Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS.These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95 (13) and 55.92 (13)°, respectively].The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20 (12) and -144.15 (12)°, respectively; q = quaternary and ph = phen-yl].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20 (12) and -144.15 (12)°, respectively; q = quaternary and ph = phen-yl]. The independent mol-ecules are linked into a dimeric aggregate by N-H⋯S hydrogen bonds and an eight-membered thio-amide {⋯H-N-C=S}(2) synthon.

No MeSH data available.


Related in: MedlinePlus