Limits...
syn-5,10,15-Tris(dichloro-meth-yl)-5,10,15-trihy-droxy-5H-diindeno-[1,2-a:1',2'-c]fluorene dichloro-methane 0.82-solvate.

Morrison GW, Fronczek FR, Watkins SF - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy-droxy and dichloro-methyl substituents at stereocenters 5R/S, 10R/S and 15R/S.C-Cl distances are in the range 1.759 (4)-1.783 (3) Å.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.

ABSTRACT
The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy-droxy and dichloro-methyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C-Cl distances are in the range 1.759 (4)-1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloro-methane solvent mol-ecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Only one of the OH groups forms a hydrogen bond, which is inter-molecular to another OH group, forming centrosymmetric dimers in the crystal.

No MeSH data available.


Related in: MedlinePlus

Hydrogen-bonded dimer with 40% probability ellipsoids. Only OH hydrogen atoms are illustrated.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379341&req=5

Fap2: Hydrogen-bonded dimer with 40% probability ellipsoids. Only OH hydrogen atoms are illustrated.


syn-5,10,15-Tris(dichloro-meth-yl)-5,10,15-trihy-droxy-5H-diindeno-[1,2-a:1',2'-c]fluorene dichloro-methane 0.82-solvate.

Morrison GW, Fronczek FR, Watkins SF - Acta Crystallogr Sect E Struct Rep Online (2012)

Hydrogen-bonded dimer with 40% probability ellipsoids. Only OH hydrogen atoms are illustrated.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379341&req=5

Fap2: Hydrogen-bonded dimer with 40% probability ellipsoids. Only OH hydrogen atoms are illustrated.
Bottom Line: The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy-droxy and dichloro-methyl substituents at stereocenters 5R/S, 10R/S and 15R/S.C-Cl distances are in the range 1.759 (4)-1.783 (3) Å.D65, 148-155].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.

ABSTRACT
The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy-droxy and dichloro-methyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C-Cl distances are in the range 1.759 (4)-1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloro-methane solvent mol-ecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Only one of the OH groups forms a hydrogen bond, which is inter-molecular to another OH group, forming centrosymmetric dimers in the crystal.

No MeSH data available.


Related in: MedlinePlus