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2-Amino-cyclo-hexan-1-aminium thio-cyanate.

Salem HF, Hasbullah SA, Yamin BM - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(6)H(15)N(2) (+)·NCS(-), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio-cyanate and cyclo-hexane-1,2-diamine.The cyclo-hexane ring adopts a chair conformation.In the crystal, N-H⋯S and N-H⋯N inter-actions involving the thio-cyanate anion and both the amine and the aminium N atoms link the mol-ecules, forming two-dimensional networks parallel to (001).

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Affiliation: School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, UKM 43500 Bangi Selangor, Malaysia.

ABSTRACT
The title compound, C(6)H(15)N(2) (+)·NCS(-), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio-cyanate and cyclo-hexane-1,2-diamine. The cyclo-hexane ring adopts a chair conformation. In the crystal, N-H⋯S and N-H⋯N inter-actions involving the thio-cyanate anion and both the amine and the aminium N atoms link the mol-ecules, forming two-dimensional networks parallel to (001).

No MeSH data available.


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Molecular packing of (I) viewed down c axis. The dashed lines indicate intermolecular hydrogen bonds.
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Fap2: Molecular packing of (I) viewed down c axis. The dashed lines indicate intermolecular hydrogen bonds.


2-Amino-cyclo-hexan-1-aminium thio-cyanate.

Salem HF, Hasbullah SA, Yamin BM - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular packing of (I) viewed down c axis. The dashed lines indicate intermolecular hydrogen bonds.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379321&req=5

Fap2: Molecular packing of (I) viewed down c axis. The dashed lines indicate intermolecular hydrogen bonds.
Bottom Line: The title compound, C(6)H(15)N(2) (+)·NCS(-), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio-cyanate and cyclo-hexane-1,2-diamine.The cyclo-hexane ring adopts a chair conformation.In the crystal, N-H⋯S and N-H⋯N inter-actions involving the thio-cyanate anion and both the amine and the aminium N atoms link the mol-ecules, forming two-dimensional networks parallel to (001).

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Chemical Sciences and Food Technology, Universiti Kebangsaan Malaysia, UKM 43500 Bangi Selangor, Malaysia.

ABSTRACT
The title compound, C(6)H(15)N(2) (+)·NCS(-), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio-cyanate and cyclo-hexane-1,2-diamine. The cyclo-hexane ring adopts a chair conformation. In the crystal, N-H⋯S and N-H⋯N inter-actions involving the thio-cyanate anion and both the amine and the aminium N atoms link the mol-ecules, forming two-dimensional networks parallel to (001).

No MeSH data available.


Related in: MedlinePlus