Limits...
9-(2-Bromo-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Sieradzan A, Krzymiński K, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°.The carb-oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton.The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-Br⋯π and π-π contacts [centroid-centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C-H⋯O, C-F⋯π and S-O⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°. The carb-oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice.

No MeSH data available.


The molecular structure of the title compound showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2, Cg3 and Cg4 denote the ring centroids. The C–H···O hydrogen bond is represented by a dashed line.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379313&req=5

Fap1: The molecular structure of the title compound showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2, Cg3 and Cg4 denote the ring centroids. The C–H···O hydrogen bond is represented by a dashed line.


9-(2-Bromo-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.

Trzybiński D, Sieradzan A, Krzymiński K, Błażejowski J - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2, Cg3 and Cg4 denote the ring centroids. The C–H···O hydrogen bond is represented by a dashed line.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379313&req=5

Fap1: The molecular structure of the title compound showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 25% probability level and H atoms are shown as small spheres of arbitrary radius. Cg1, Cg2, Cg3 and Cg4 denote the ring centroids. The C–H···O hydrogen bond is represented by a dashed line.
Bottom Line: The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°.The carb-oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton.The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

ABSTRACT
In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-Br⋯π and π-π contacts [centroid-centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C-H⋯O, C-F⋯π and S-O⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°. The carb-oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice.

No MeSH data available.