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2,4-Dioxa-λ(6)-thia-tetra-cyclo-[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione.

Ioannou S, Moushi E - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms.The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C-O bonds.The C-C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C-C bonds of the mol-ecule due to the stretch of the cage structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, University of Cyprus, Nicosia 1678, Cyprus.

ABSTRACT
The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C-O bonds. The C-C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C-C bonds of the mol-ecule due to the stretch of the cage structure.

No MeSH data available.


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Preparation of the title compound and the experimental path of noradamantene formation.
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Fap3: Preparation of the title compound and the experimental path of noradamantene formation.


2,4-Dioxa-λ(6)-thia-tetra-cyclo-[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione.

Ioannou S, Moushi E - Acta Crystallogr Sect E Struct Rep Online (2012)

Preparation of the title compound and the experimental path of noradamantene formation.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379310&req=5

Fap3: Preparation of the title compound and the experimental path of noradamantene formation.
Bottom Line: The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms.The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C-O bonds.The C-C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C-C bonds of the mol-ecule due to the stretch of the cage structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Chemistry Department, University of Cyprus, Nicosia 1678, Cyprus.

ABSTRACT
The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C-O bonds. The C-C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C-C bonds of the mol-ecule due to the stretch of the cage structure.

No MeSH data available.


Related in: MedlinePlus