View of the three-dimensional supramolecular-like struc

4,4'-Bipyridine-terephthalic acid (1/1). Koteswara Rao V, Zeller M, Lovelace-Cameron SR - Acta Crystallogr Sect E Struct Rep Online (2012) Bottom Line: The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol-ecule of each moiety, 4,4'-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers.The chains are further connected through C-H⋯O inter-actions giving sheets in (012).The sheets are linked via π-π inter-actions between the bpy rings and the bdc-bpy rings [centroid-centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra-molecular layer-like structure. View Article: PubMed Central - HTML - PubMed Affiliation: Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, OH 44555, USA. ABSTRACT The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol-ecule of each moiety, 4,4'-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong inter-molecular O-H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C-H⋯O inter-actions giving sheets in (012). The sheets are linked via π-π inter-actions between the bpy rings and the bdc-bpy rings [centroid-centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra-molecular layer-like structure. No MeSH data available.	© Copyright Policy - open-access Related In: Results - Collection License Show All Figures getmorefigures.php?uid=PMC3379304&req=5 Fap3: View of the three-dimensional supramolecular-like structure. Green dots represent the C-H···O hydrogen bonds connecting parallel stacks of chains. The purple arrows represent the π-π interactions within the π-stacks [see Table 1 for details].

4,4'-Bipyridine-terephthalic acid (1/1).

Koteswara Rao V, Zeller M, Lovelace-Cameron SR - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol-ecule of each moiety, 4,4'-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers.The chains are further connected through C-H⋯O inter-actions giving sheets in (012).The sheets are linked via π-π inter-actions between the bpy rings and the bdc-bpy rings [centroid-centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra-molecular layer-like structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, OH 44555, USA.

ABSTRACT

The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol-ecule of each moiety, 4,4'-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong inter-molecular O-H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C-H⋯O inter-actions giving sheets in (012). The sheets are linked via π-π inter-actions between the bpy rings and the bdc-bpy rings [centroid-centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra-molecular layer-like structure.

No MeSH data available.

View of the three-dimensional supramolecular-like structure. Green dots represent the C-H···O hydrogen bonds connecting parallel stacks of chains. The purple arrows represent the π-π interactions within the π-stacks [see Table 1 for details].

Related In: Results - Collection

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Fap3: View of the three-dimensional supramolecular-like structure. Green dots represent the C-H···O hydrogen bonds connecting parallel stacks of chains. The purple arrows represent the π-π interactions within the π-stacks [see Table 1 for details].