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2-(Pyridin-2-yl)-1,3-oxathiane.

Turner D, Fratini A, Turro C, Check M, Hunter C - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring.The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes.The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring.

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ABSTRACT
The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S-C-C-N torsion angle is 69.07 (14)°. In the crystal, mol-ecules aggregate as centrosymmetric pairs connected by pairs of C-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound. Thermal ellipsoids are drawn at 50% probability for non-H atoms.
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Fap1: The molecular structure of the title compound. Thermal ellipsoids are drawn at 50% probability for non-H atoms.


2-(Pyridin-2-yl)-1,3-oxathiane.

Turner D, Fratini A, Turro C, Check M, Hunter C - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound. Thermal ellipsoids are drawn at 50% probability for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379271&req=5

Fap1: The molecular structure of the title compound. Thermal ellipsoids are drawn at 50% probability for non-H atoms.
Bottom Line: The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring.The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes.The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C-C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S-C-C-N torsion angle is 69.07 (14)°. In the crystal, mol-ecules aggregate as centrosymmetric pairs connected by pairs of C-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus