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2-Cyano-1-methyl-pyridinium nitrate.

Koplitz LV, Mague JT, Kammer MN, McCormick CA, Renfro HE, Vumbaco DJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The inter-layer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å.Two-dimensional C-H⋯O hydrogen-bonded networks link cations to anions, while C-H⋯N inter-actions link cations within each layer.Anion-π inter-actions with the cations assist in binding the layers together.

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ABSTRACT
In the title compound, C(7)H(7)N(2) (+)·NO(3) (-), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The inter-layer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimensional C-H⋯O hydrogen-bonded networks link cations to anions, while C-H⋯N inter-actions link cations within each layer. Anion-π inter-actions with the cations assist in binding the layers together.

No MeSH data available.


Related in: MedlinePlus

The packing viewed down the c axis showing the interlayer interactions.
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Fap2: The packing viewed down the c axis showing the interlayer interactions.


2-Cyano-1-methyl-pyridinium nitrate.

Koplitz LV, Mague JT, Kammer MN, McCormick CA, Renfro HE, Vumbaco DJ - Acta Crystallogr Sect E Struct Rep Online (2012)

The packing viewed down the c axis showing the interlayer interactions.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379252&req=5

Fap2: The packing viewed down the c axis showing the interlayer interactions.
Bottom Line: The inter-layer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å.Two-dimensional C-H⋯O hydrogen-bonded networks link cations to anions, while C-H⋯N inter-actions link cations within each layer.Anion-π inter-actions with the cations assist in binding the layers together.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, C(7)H(7)N(2) (+)·NO(3) (-), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The inter-layer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimensional C-H⋯O hydrogen-bonded networks link cations to anions, while C-H⋯N inter-actions link cations within each layer. Anion-π inter-actions with the cations assist in binding the layers together.

No MeSH data available.


Related in: MedlinePlus