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N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

Tayamon S, Ravoof TB, Tahir MI, Crouse KA, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°].Supra-molecular chains sustained by N-H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure.The chains are consolidated into a three-dimensional architecture by C-H⋯O and C-H⋯N inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title hydrazonodithio-ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C-N-N-C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supra-molecular chains sustained by N-H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C-H⋯O and C-H⋯N inter-actions.

No MeSH data available.


Related in: MedlinePlus

A view in projection down the a axis of the unit-cell contents for (I). The N—H···O, C—H···O and C—H···N interactions are shown as blue orange and brown dashed lines, respectively.
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Fap3: A view in projection down the a axis of the unit-cell contents for (I). The N—H···O, C—H···O and C—H···N interactions are shown as blue orange and brown dashed lines, respectively.


N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

Tayamon S, Ravoof TB, Tahir MI, Crouse KA, Tiekink ER - Acta Crystallogr Sect E Struct Rep Online (2012)

A view in projection down the a axis of the unit-cell contents for (I). The N—H···O, C—H···O and C—H···N interactions are shown as blue orange and brown dashed lines, respectively.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379243&req=5

Fap3: A view in projection down the a axis of the unit-cell contents for (I). The N—H···O, C—H···O and C—H···N interactions are shown as blue orange and brown dashed lines, respectively.
Bottom Line: The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°].Supra-molecular chains sustained by N-H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure.The chains are consolidated into a three-dimensional architecture by C-H⋯O and C-H⋯N inter-actions.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title hydrazonodithio-ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C-N-N-C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supra-molecular chains sustained by N-H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C-H⋯O and C-H⋯N inter-actions.

No MeSH data available.


Related in: MedlinePlus