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[2-({Benz-yl[2-(benz-yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth-yl)imino-meth-yl]benz-yl}amino)-eth-yl]aza-nium-yl}meth-yl)-4-methyl-6-[(pyridin-2-ylmeth-yl)imino-meth-yl]phenolato]nickel(II) perchlorate methanol disolvate.

Liu M, Mao JW, Pan ZQ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand.An intra-molecular bifurcated N-H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule.In the crystal, the components are connected by O-H⋯O and C-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N-H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the components are connected by O-H⋯O and C-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
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Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.


[2-({Benz-yl[2-(benz-yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth-yl)imino-meth-yl]benz-yl}amino)-eth-yl]aza-nium-yl}meth-yl)-4-methyl-6-[(pyridin-2-ylmeth-yl)imino-meth-yl]phenolato]nickel(II) perchlorate methanol disolvate.

Liu M, Mao JW, Pan ZQ - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379195&req=5

Fap1: Molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
Bottom Line: In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand.An intra-molecular bifurcated N-H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule.In the crystal, the components are connected by O-H⋯O and C-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N-H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the components are connected by O-H⋯O and C-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus