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Bis(triethyl-ammonium) tetra-chlorido-cobaltate(II).

Azadbakht R, Hadadzadeh H, Amiri Rudbari H - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The latter are featureless while the [CoCl(4)](2-) anion exhibits typical Co-Cl bond lengths [2.2428 (15)-2.2847 (16) Å] and a Cl-Co-Cl angular range of 107.58 (6)-112.73 (7)°.In the crystal, N-H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2-) anion generate discrete ion triplets.The two Co-Cl bonds involved in these inter-actions are slightly longer than the remaining two.

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ABSTRACT
The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2-) anion and two independent triethyl-ammonium cations. The latter are featureless while the [CoCl(4)](2-) anion exhibits typical Co-Cl bond lengths [2.2428 (15)-2.2847 (16) Å] and a Cl-Co-Cl angular range of 107.58 (6)-112.73 (7)°. In the crystal, N-H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2-) anion generate discrete ion triplets. The two Co-Cl bonds involved in these inter-actions are slightly longer than the remaining two.

No MeSH data available.


The asymmetric unit with atom labels and 50% probability ellipsoids for non-H atoms. Hydrogen bonds are shown as dashed lines.
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Fap1: The asymmetric unit with atom labels and 50% probability ellipsoids for non-H atoms. Hydrogen bonds are shown as dashed lines.


Bis(triethyl-ammonium) tetra-chlorido-cobaltate(II).

Azadbakht R, Hadadzadeh H, Amiri Rudbari H - Acta Crystallogr Sect E Struct Rep Online (2012)

The asymmetric unit with atom labels and 50% probability ellipsoids for non-H atoms. Hydrogen bonds are shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379194&req=5

Fap1: The asymmetric unit with atom labels and 50% probability ellipsoids for non-H atoms. Hydrogen bonds are shown as dashed lines.
Bottom Line: The latter are featureless while the [CoCl(4)](2-) anion exhibits typical Co-Cl bond lengths [2.2428 (15)-2.2847 (16) Å] and a Cl-Co-Cl angular range of 107.58 (6)-112.73 (7)°.In the crystal, N-H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2-) anion generate discrete ion triplets.The two Co-Cl bonds involved in these inter-actions are slightly longer than the remaining two.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2-) anion and two independent triethyl-ammonium cations. The latter are featureless while the [CoCl(4)](2-) anion exhibits typical Co-Cl bond lengths [2.2428 (15)-2.2847 (16) Å] and a Cl-Co-Cl angular range of 107.58 (6)-112.73 (7)°. In the crystal, N-H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2-) anion generate discrete ion triplets. The two Co-Cl bonds involved in these inter-actions are slightly longer than the remaining two.

No MeSH data available.