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catena-Poly[[bis-(nitrato-κO)cadmium]bis-[μ-1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene-κ(2)N(4):N(4')]].

Zhang HK, Wang X, Wang S, Wang XD - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry.The ligands link different Cd(II) ions into a ribbon-like structure along [001].Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

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ABSTRACT
In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

No MeSH data available.


A portion of the ribbon-like structure in the title compound. H atoms and disordered O atoms have been omitted for clarity.
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Fap2: A portion of the ribbon-like structure in the title compound. H atoms and disordered O atoms have been omitted for clarity.


catena-Poly[[bis-(nitrato-κO)cadmium]bis-[μ-1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene-κ(2)N(4):N(4')]].

Zhang HK, Wang X, Wang S, Wang XD - Acta Crystallogr Sect E Struct Rep Online (2012)

A portion of the ribbon-like structure in the title compound. H atoms and disordered O atoms have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379191&req=5

Fap2: A portion of the ribbon-like structure in the title compound. H atoms and disordered O atoms have been omitted for clarity.
Bottom Line: In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry.The ligands link different Cd(II) ions into a ribbon-like structure along [001].Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

No MeSH data available.