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catena-Poly[[bis-(nitrato-κO)cadmium]bis-[μ-1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene-κ(2)N(4):N(4')]].

Zhang HK, Wang X, Wang S, Wang XD - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry.The ligands link different Cd(II) ions into a ribbon-like structure along [001].Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

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ABSTRACT
In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

No MeSH data available.


The molecular structure of the title compound, showing displacement ellipsoids at the 50% probability level for non-H atoms. Only the main component of the disordered nitrate anion is shown. Symmetry codes: (i) 1-x, 1-y, 1-z; (ii) 1-x, 1-y, -z; (iii) x, y, 1+z.
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Fap1: The molecular structure of the title compound, showing displacement ellipsoids at the 50% probability level for non-H atoms. Only the main component of the disordered nitrate anion is shown. Symmetry codes: (i) 1-x, 1-y, 1-z; (ii) 1-x, 1-y, -z; (iii) x, y, 1+z.


catena-Poly[[bis-(nitrato-κO)cadmium]bis-[μ-1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene-κ(2)N(4):N(4')]].

Zhang HK, Wang X, Wang S, Wang XD - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound, showing displacement ellipsoids at the 50% probability level for non-H atoms. Only the main component of the disordered nitrate anion is shown. Symmetry codes: (i) 1-x, 1-y, 1-z; (ii) 1-x, 1-y, -z; (iii) x, y, 1+z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379191&req=5

Fap1: The molecular structure of the title compound, showing displacement ellipsoids at the 50% probability level for non-H atoms. Only the main component of the disordered nitrate anion is shown. Symmetry codes: (i) 1-x, 1-y, 1-z; (ii) 1-x, 1-y, -z; (iii) x, y, 1+z.
Bottom Line: In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry.The ligands link different Cd(II) ions into a ribbon-like structure along [001].Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).

No MeSH data available.