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Poly[bis-(μ(6)-benzene-1,3,5-tricarboxyl-ato-κ(7)O(1),O(1'):O(1'):O(3):O(3'):O(5):O(5'))tetra-kis-(dimethyl-formamide-κO)trimagnesium(II)].

Luczyńska-Szymczak K, Starosta W, Leciejewicz J - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: One Mg(II) ion is octa-hedrally coordinated by six carboxyl-ate O atoms.The other two cations are each octa-hedrally coordinated by four carboxyl-ate O atoms and two O atoms donated by two DMF mol-ecules: in one, the DMF mol-ecules are cis and in the other they are trans.The three Mg(II) octa-hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa, Poland.

ABSTRACT
The asymmetric unit of the polymeric title compound, [Mg(3)(C(9)H(3)O(6))(2)(C(3)H(7)NO)(4)](n), contains three Mg(II) ions bridged by carboxyl-ate O atoms from two fully deprotonated benzene-1,3,5-tricarboxyl-ate (BTC) trianions and four metal-coordinated dimethyl-formamide (DMF) mol-ecules. One Mg(II) ion is octa-hedrally coordinated by six carboxyl-ate O atoms. The other two cations are each octa-hedrally coordinated by four carboxyl-ate O atoms and two O atoms donated by two DMF mol-ecules: in one, the DMF mol-ecules are cis and in the other they are trans. The three Mg(II) octa-hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.

No MeSH data available.


Related in: MedlinePlus

Packing diagram of the structure viewed along the a axis.
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Related In: Results  -  Collection

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Fap2: Packing diagram of the structure viewed along the a axis.


Poly[bis-(μ(6)-benzene-1,3,5-tricarboxyl-ato-κ(7)O(1),O(1'):O(1'):O(3):O(3'):O(5):O(5'))tetra-kis-(dimethyl-formamide-κO)trimagnesium(II)].

Luczyńska-Szymczak K, Starosta W, Leciejewicz J - Acta Crystallogr Sect E Struct Rep Online (2012)

Packing diagram of the structure viewed along the a axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379189&req=5

Fap2: Packing diagram of the structure viewed along the a axis.
Bottom Line: One Mg(II) ion is octa-hedrally coordinated by six carboxyl-ate O atoms.The other two cations are each octa-hedrally coordinated by four carboxyl-ate O atoms and two O atoms donated by two DMF mol-ecules: in one, the DMF mol-ecules are cis and in the other they are trans.The three Mg(II) octa-hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute of Nuclear Chemistry and Technology, ul. Dorodna 16, 03-195 Warszawa, Poland.

ABSTRACT
The asymmetric unit of the polymeric title compound, [Mg(3)(C(9)H(3)O(6))(2)(C(3)H(7)NO)(4)](n), contains three Mg(II) ions bridged by carboxyl-ate O atoms from two fully deprotonated benzene-1,3,5-tricarboxyl-ate (BTC) trianions and four metal-coordinated dimethyl-formamide (DMF) mol-ecules. One Mg(II) ion is octa-hedrally coordinated by six carboxyl-ate O atoms. The other two cations are each octa-hedrally coordinated by four carboxyl-ate O atoms and two O atoms donated by two DMF mol-ecules: in one, the DMF mol-ecules are cis and in the other they are trans. The three Mg(II) octa-hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.

No MeSH data available.


Related in: MedlinePlus