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Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-κ(2)P,S]copper(I) hexa-fluoridophosphate.

Zhang JJ, Hu F, Duan TK, Chen Q, Zhang QF - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry.The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring.The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

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ABSTRACT
In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title compound, with displacement ellipsoids at the 50% probability level. [Symmetry codes: (A) 1/2-x, 1-y, z; (B) 1-x, y, 1/2-z.]
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Fap1: Molecular structure of the title compound, with displacement ellipsoids at the 50% probability level. [Symmetry codes: (A) 1/2-x, 1-y, z; (B) 1-x, y, 1/2-z.]


Bis[(diphenyl-phosphanylmeth-yl)diphenyl-phosphane sulfide-κ(2)P,S]copper(I) hexa-fluoridophosphate.

Zhang JJ, Hu F, Duan TK, Chen Q, Zhang QF - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title compound, with displacement ellipsoids at the 50% probability level. [Symmetry codes: (A) 1/2-x, 1-y, z; (B) 1-x, y, 1/2-z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379181&req=5

Fap1: Molecular structure of the title compound, with displacement ellipsoids at the 50% probability level. [Symmetry codes: (A) 1/2-x, 1-y, z; (B) 1-x, y, 1/2-z.]
Bottom Line: In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry.The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring.The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

No MeSH data available.


Related in: MedlinePlus