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catena-Poly[[[bis-(nitrato-κO)copper(II)]-bis-[μ-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-κ(2)N(3):N(3')]] dihydrate].

Liu GX - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites.The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°.The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, People's Republic of China.

ABSTRACT
In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra-molecular structure by O-H⋯O and C-H⋯O hydrogen bonds.

No MeSH data available.


Lateral view of the two-dimensional sheet in the bc plane of the title complex. Hydrogen atoms, water molecules and nitrate anions are omitted for clarity.
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Fap2: Lateral view of the two-dimensional sheet in the bc plane of the title complex. Hydrogen atoms, water molecules and nitrate anions are omitted for clarity.


catena-Poly[[[bis-(nitrato-κO)copper(II)]-bis-[μ-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-κ(2)N(3):N(3')]] dihydrate].

Liu GX - Acta Crystallogr Sect E Struct Rep Online (2012)

Lateral view of the two-dimensional sheet in the bc plane of the title complex. Hydrogen atoms, water molecules and nitrate anions are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379180&req=5

Fap2: Lateral view of the two-dimensional sheet in the bc plane of the title complex. Hydrogen atoms, water molecules and nitrate anions are omitted for clarity.
Bottom Line: In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites.The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°.The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, People's Republic of China.

ABSTRACT
In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa-hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis-(imidazol-1-yl)-5-methyl-benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra-molecular structure by O-H⋯O and C-H⋯O hydrogen bonds.

No MeSH data available.