Limits...
[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-[tris-(2-chloro-eth-yl) phosphite-3κP]-triangulo-triruthenium(0).

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Each Ru atom bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°.In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis-(di-o-tolyl-phosphan-yl)methane ligand bridges one Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

No MeSH data available.


Related in: MedlinePlus

The crystal structure of the title compound, viewed down the c axis. H atoms not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379179&req=5

Fap2: The crystal structure of the title compound, viewed down the c axis. H atoms not involved in hydrogen bonds (dashed lines) have been omitted for clarity.


[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-[tris-(2-chloro-eth-yl) phosphite-3κP]-triangulo-triruthenium(0).

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

The crystal structure of the title compound, viewed down the c axis. H atoms not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379179&req=5

Fap2: The crystal structure of the title compound, viewed down the c axis. H atoms not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
Bottom Line: Each Ru atom bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°.In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis-(di-o-tolyl-phosphan-yl)methane ligand bridges one Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

No MeSH data available.


Related in: MedlinePlus