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[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-[tris-(2-chloro-eth-yl) phosphite-3κP]-triangulo-triruthenium(0).

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: Each Ru atom bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°.In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

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ABSTRACT
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis-(di-o-tolyl-phosphan-yl)methane ligand bridges one Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

No MeSH data available.


The molecular structure of the title compound showing 50% probability displacement ellipsoids for non-H atoms.
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Fap1: The molecular structure of the title compound showing 50% probability displacement ellipsoids for non-H atoms.


[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-[tris-(2-chloro-eth-yl) phosphite-3κP]-triangulo-triruthenium(0).

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound showing 50% probability displacement ellipsoids for non-H atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379179&req=5

Fap1: The molecular structure of the title compound showing 50% probability displacement ellipsoids for non-H atoms.
Bottom Line: Each Ru atom bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°.In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis-(di-o-tolyl-phosphan-yl)methane ligand bridges one Ru-Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenyl-phosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds into chains along [100].

No MeSH data available.