Limits...
A triclinic polymorph of bis-(μ-di-tert-butyl-phosphanido)bis-[(di-tert-butyl-phosphane)palladium(I)].

Breunig J, Lerner HW, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: A new polymorph of the title compound, [Pd(2)(C(8)H(18)P)(2)(C(8)H(19)P)(2)], has been found.Organo-met.The crystal packing patterns, on the other hand, are slightly different.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany.

ABSTRACT
A new polymorph of the title compound, [Pd(2)(C(8)H(18)P)(2)(C(8)H(19)P)(2)], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992 ▶), J. Organo-met. Chem.423, 263-270] crystallizes in the monoclinic C2/c space group. The title compound features a dinuclear palladium complex with a planar central Pd(2)(μ-P)(2) core (r.m.s. deviation = 0.003 Å). The Pd-Pd distance of 2.5988 (5) Å is within the range of a Pd(I)-Pd(I) bond. The mol-ecules of both polymorphs are located on a crystallographic centre of inversion. The mol-ecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different.

No MeSH data available.


Packing diagram of the monoclinic polymorph of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379177&req=5

Fap5: Packing diagram of the monoclinic polymorph of the title compound.


A triclinic polymorph of bis-(μ-di-tert-butyl-phosphanido)bis-[(di-tert-butyl-phosphane)palladium(I)].

Breunig J, Lerner HW, Bolte M - Acta Crystallogr Sect E Struct Rep Online (2012)

Packing diagram of the monoclinic polymorph of the title compound.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379177&req=5

Fap5: Packing diagram of the monoclinic polymorph of the title compound.
Bottom Line: A new polymorph of the title compound, [Pd(2)(C(8)H(18)P)(2)(C(8)H(19)P)(2)], has been found.Organo-met.The crystal packing patterns, on the other hand, are slightly different.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt am Main, Germany.

ABSTRACT
A new polymorph of the title compound, [Pd(2)(C(8)H(18)P)(2)(C(8)H(19)P)(2)], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992 ▶), J. Organo-met. Chem.423, 263-270] crystallizes in the monoclinic C2/c space group. The title compound features a dinuclear palladium complex with a planar central Pd(2)(μ-P)(2) core (r.m.s. deviation = 0.003 Å). The Pd-Pd distance of 2.5988 (5) Å is within the range of a Pd(I)-Pd(I) bond. The mol-ecules of both polymorphs are located on a crystallographic centre of inversion. The mol-ecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different.

No MeSH data available.