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Aqua-bis-[N'-(1,3-dithio-lan-2-ylidene)-2-hy-droxy-benzohydrazidato(0.5-)-κ(2)N',O]sodium(I).

Bouchameni C, Beghidja C, Beghidja A, Boutebdja M - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule.The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis.Mol-ecules pack as discrete units and the crystal packing is stabilized by strong O-H⋯O hydrogen bonds, which give rise to chains along [010]; the chains are inter-linked by strong O-H⋯O hydrogen bonds.

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Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Mentouri, 25000 Constantine, Algeria.

ABSTRACT
The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule. The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis. Intra-molecular N-H⋯O hydrogen bonds occur. Mol-ecules pack as discrete units and the crystal packing is stabilized by strong O-H⋯O hydrogen bonds, which give rise to chains along [010]; the chains are inter-linked by strong O-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

Mercury view of the crystal structure of title compound along the a axis showing the two-dimensional network via a strong hydrogen bonds through O—H···O atoms.
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Fap2: Mercury view of the crystal structure of title compound along the a axis showing the two-dimensional network via a strong hydrogen bonds through O—H···O atoms.


Aqua-bis-[N'-(1,3-dithio-lan-2-ylidene)-2-hy-droxy-benzohydrazidato(0.5-)-κ(2)N',O]sodium(I).

Bouchameni C, Beghidja C, Beghidja A, Boutebdja M - Acta Crystallogr Sect E Struct Rep Online (2012)

Mercury view of the crystal structure of title compound along the a axis showing the two-dimensional network via a strong hydrogen bonds through O—H···O atoms.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379147&req=5

Fap2: Mercury view of the crystal structure of title compound along the a axis showing the two-dimensional network via a strong hydrogen bonds through O—H···O atoms.
Bottom Line: The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule.The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis.Mol-ecules pack as discrete units and the crystal packing is stabilized by strong O-H⋯O hydrogen bonds, which give rise to chains along [010]; the chains are inter-linked by strong O-H⋯O hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Mentouri, 25000 Constantine, Algeria.

ABSTRACT
The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule. The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a twofold rotation axis. Intra-molecular N-H⋯O hydrogen bonds occur. Mol-ecules pack as discrete units and the crystal packing is stabilized by strong O-H⋯O hydrogen bonds, which give rise to chains along [010]; the chains are inter-linked by strong O-H⋯O hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus