Limits...
Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris-(pyridin-2-yl)-2-imidazoline-κ(3)N(2),N(3),N(4)]ytterbium(III) chloride.

Baez-Castro A, Höpfl H, Parra-Hake M, Cruz-Enriquez A, Campos-Gaxiola JJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions.Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions. Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

Perspective view of a fragment of the linear supramolecular chain along [010] with the N—H···Cl, O—H···Cl and O—H···N hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379138&req=5

Fap2: Perspective view of a fragment of the linear supramolecular chain along [010] with the N—H···Cl, O—H···Cl and O—H···N hydrogen bonds shown as dashed lines.


Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris-(pyridin-2-yl)-2-imidazoline-κ(3)N(2),N(3),N(4)]ytterbium(III) chloride.

Baez-Castro A, Höpfl H, Parra-Hake M, Cruz-Enriquez A, Campos-Gaxiola JJ - Acta Crystallogr Sect E Struct Rep Online (2012)

Perspective view of a fragment of the linear supramolecular chain along [010] with the N—H···Cl, O—H···Cl and O—H···N hydrogen bonds shown as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379138&req=5

Fap2: Perspective view of a fragment of the linear supramolecular chain along [010] with the N—H···Cl, O—H···Cl and O—H···N hydrogen bonds shown as dashed lines.
Bottom Line: In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions.Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-penta-gonal-bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris-(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol mol-ecules and two Cl(-) anions. Chains are formed along [010] through N-H⋯Cl, O-H⋯Cl and O-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus