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[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro-form disolvate.

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand.In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].

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ABSTRACT
In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis-(di-o-tolyl-phosphan-yl)methane (dtpm) ligand bridges one of the Ru-Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].

No MeSH data available.


Related in: MedlinePlus

The crystal structure of the title compound, viewed along the a axis. H atoms and solvents molecules not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
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Fap2: The crystal structure of the title compound, viewed along the a axis. H atoms and solvents molecules not involved in hydrogen bonds (dashed lines) have been omitted for clarity.


[μ-Bis(di-o-tolyl-phosphan-yl)methane-1:2κ(2)P:P']nona-carbonyl-1κ(3)C,2κ(3)C,3κ(3)C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro-form disolvate.

Shawkataly OB, Khan IA, Sirat SS, Quah CK, Fun HK - Acta Crystallogr Sect E Struct Rep Online (2012)

The crystal structure of the title compound, viewed along the a axis. H atoms and solvents molecules not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379136&req=5

Fap2: The crystal structure of the title compound, viewed along the a axis. H atoms and solvents molecules not involved in hydrogen bonds (dashed lines) have been omitted for clarity.
Bottom Line: All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands.The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand.In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis-(di-o-tolyl-phosphan-yl)methane (dtpm) ligand bridges one of the Ru-Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl-phosphanyl groups of the dtpm ligand. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into chains along [010].

No MeSH data available.


Related in: MedlinePlus