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Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc.

Dehghani A, M Amini M, Najafi E, Tadjarodi A, Notash B - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield.The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions.There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å.

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ABSTRACT
The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å.

No MeSH data available.


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The molecular structure of the title compound, ellipsoids drawn at 30% probability level.
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Fap1: The molecular structure of the title compound, ellipsoids drawn at 30% probability level.


Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc.

Dehghani A, M Amini M, Najafi E, Tadjarodi A, Notash B - Acta Crystallogr Sect E Struct Rep Online (2012)

The molecular structure of the title compound, ellipsoids drawn at 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379135&req=5

Fap1: The molecular structure of the title compound, ellipsoids drawn at 30% probability level.
Bottom Line: The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield.The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions.There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å.

No MeSH data available.


Related in: MedlinePlus