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Diaqua-bis-{4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonato-κ(2)N,N'}nickel(II) tetra-hydrate.

Li CZ, Huang XR - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071 (3)-2.121 (3) Å and Ni-O = 2.071 (2) and 2.073 (3) Å].In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H⋯O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Qinzhou University, Qinzhou, Guangxi 535000, People's Republic of China.

ABSTRACT
In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071 (3)-2.121 (3) Å and Ni-O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H⋯O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

No MeSH data available.


The packing of the title complex, showing the two-dimensional sheet structure in the ac plane.
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Fap2: The packing of the title complex, showing the two-dimensional sheet structure in the ac plane.


Diaqua-bis-{4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonato-κ(2)N,N'}nickel(II) tetra-hydrate.

Li CZ, Huang XR - Acta Crystallogr Sect E Struct Rep Online (2012)

The packing of the title complex, showing the two-dimensional sheet structure in the ac plane.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379134&req=5

Fap2: The packing of the title complex, showing the two-dimensional sheet structure in the ac plane.
Bottom Line: In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071 (3)-2.121 (3) Å and Ni-O = 2.071 (2) and 2.073 (3) Å].In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H⋯O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

View Article: PubMed Central - HTML - PubMed

Affiliation: College of Chemistry and Chemical Engineering, Qinzhou University, Qinzhou, Guangxi 535000, People's Republic of China.

ABSTRACT
In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071 (3)-2.121 (3) Å and Ni-O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H⋯O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

No MeSH data available.