Limits...
Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')iron(III).

Perdih F - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in a slightly distorted octa-hedral environment.Fe-O bond lengths are in the range 1.9818 (18)-1.9957 (18) Å.The trans O-Fe-O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)-100.68 (12)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in a slightly distorted octa-hedral environment. Fe-O bond lengths are in the range 1.9818 (18)-1.9957 (18) Å. The trans O-Fe-O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)-100.68 (12)°. In the crystal, mol-ecules are linked via C-H⋯Cl inter-actions.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 3/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC3379132&req=5

Fap1: Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 3/2.


Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')iron(III).

Perdih F - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 3/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379132&req=5

Fap1: Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 3/2.
Bottom Line: In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in a slightly distorted octa-hedral environment.Fe-O bond lengths are in the range 1.9818 (18)-1.9957 (18) Å.The trans O-Fe-O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)-100.68 (12)°.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in a slightly distorted octa-hedral environment. Fe-O bond lengths are in the range 1.9818 (18)-1.9957 (18) Å. The trans O-Fe-O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)-100.68 (12)°. In the crystal, mol-ecules are linked via C-H⋯Cl inter-actions.

No MeSH data available.


Related in: MedlinePlus