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Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')aluminium.

Perdih F - Acta Crystallogr Sect E Struct Rep Online (2012)

Bottom Line: In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment.Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å.In the crystal, mol-ecules are linked via C-H⋯Cl contacts.

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ABSTRACT
In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment. Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å. In the crystal, mol-ecules are linked via C-H⋯Cl contacts.

No MeSH data available.


Related in: MedlinePlus

Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 1/2.
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Fap1: Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 1/2.


Tris(3-chloro-pentane-2,4-dionato-κ(2)O,O')aluminium.

Perdih F - Acta Crystallogr Sect E Struct Rep Online (2012)

Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 1/2.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC3379131&req=5

Fap1: Molecular structure of the title complex showing displacement ellipsoids at the 30% probability level. Symmetry code: i = –x + 1, y, –z + 1/2.
Bottom Line: In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment.Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å.In the crystal, mol-ecules are linked via C-H⋯Cl contacts.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro-pentane-2,4-dionate ligands in an octa-hedral environment. Al-O bond lengths are in the range 1.8741 (14)-1.8772 (14) Å. In the crystal, mol-ecules are linked via C-H⋯Cl contacts.

No MeSH data available.


Related in: MedlinePlus